@misc{fang_crystallization_and_2014, 
author={Fang, L., Yan, W., Zierke, M., Richau, K., Behl, M., Kratz, K., Lendlein, A.},
title={Crystallization and Phase Segregation of Multifunctional Multiblock Copolymers in Spin Coated Thin Films Altered by Diurethane Junction Units},
year={2014},
howpublished = {journal article},
doi = {https://doi.org/10.1002/masy.201400143},
abstract = {A multiblock copolymer named PDC is composed of crystallizable oligo(p-dioxanone) (OPDO) and oligo(ε-caprolactone) (OCL) as hard and switching segments. PDC has been synthesized via connecting two oligomeric macrodiols using a diisocyanate linker such as 2,2(4), 4-trimethyl-hexamethylene diisocyanate (TMDI) or 1,6-hexamethylene diisocyanate (HDI). In this work, the surface morphologies of spin coated thin films from two PDCs (PDC-HDI and PDC-TMDI) were investigated via in-situ atomic force microscopy (AFM) to examine how the diisocyanate linkers affect the balance between crystallization and phase segregation behavior. The results demonstrated that in PDC-HDI, the crystallization of poly(ε-caprolactone) (PCL) crystals provoked a “break out” from the phase segregated morphology. On contrary, the crystallization of PCL crystals in PDC-TMDI was strictly confined in the phase segregated morphology.},
note = {Online available at: \url{https://doi.org/10.1002/masy.201400143} (DOI). Fang, L.; Yan, W.; Zierke, M.; Richau, K.; Behl, M.; Kratz, K.; Lendlein, A.: Crystallization and Phase Segregation of Multifunctional Multiblock Copolymers in Spin Coated Thin Films Altered by Diurethane Junction Units. Macromolecular Symposia. 2014. vol. 345, no. 1, 83-90. DOI: 10.1002/masy.201400143}}