@misc{pistidda_effect_of_2014, author={Pistidda, C., Karimi, F., Garroni, S., Rzeszutek, A., Bonatto Minella, C., Milanese, C., Le, T.T., Rude, L.H., Skibsted, J., Jensen, T.R., Horstmann, C., Gundlach, C., Tolkiehn, M., Pranzas, P.K., Schreyer, A., Klassen, T., Dornheim, M.}, title={Effect of the Partial Replacement of CaH2 with CaF2 in the Mixed System CaH2 + MgB2}, year={2014}, howpublished = {journal article}, doi = {https://doi.org/10.1021/jp508780b}, abstract = {In this work the effect of a partial replacement of CaH2 with CaF2 on the sorption properties of the system CaH2 + MgB2 has been studied. The first five hydrogen absorption and four desorption reactions of the CaH2 + MgB2 and 3CaH2 + CaF2 + 4MgB2 systems were investigated by means of volumetric measurements, high-pressure differential scanning calorimetric technique (HP-DSC), 11B and 19F MAS NMR spectroscopy, and in situ synchrotron radiation powder X-ray diffraction (SR-PXD). It was observed that already during the mixing of the reactants formation of a nonstoichiometric CaF2–xHx solid solution takes place. Formation of the CaF2–xHx solid solution sensibly affects the overall hydrogen sorption reactions of the system CaH2 + MgB2.}, note = {Online available at: \url{https://doi.org/10.1021/jp508780b} (DOI). Pistidda, C.; Karimi, F.; Garroni, S.; Rzeszutek, A.; Bonatto Minella, C.; Milanese, C.; Le, T.; Rude, L.; Skibsted, J.; Jensen, T.; Horstmann, C.; Gundlach, C.; Tolkiehn, M.; Pranzas, P.; Schreyer, A.; Klassen, T.; Dornheim, M.: Effect of the Partial Replacement of CaH2 with CaF2 in the Mixed System CaH2 + MgB2. The Journal of Physical Chemistry C. 2014. vol. 118, no. 49, 28409-28417. DOI: 10.1021/jp508780b}}