@misc{ceylantuncaboylu_microgels_from_2017, author={Ceylan Tuncaboylu, D., Wischke, C., Stoermann, F., Lendlein, A.}, title={Microgels from microfluidic templating and photoinduced crosslinking of cinnamylidene acetic acid modified precursors}, year={2017}, howpublished = {journal article}, doi = {https://doi.org/10.1016/j.reactfunctpolym.2016.12.015}, abstract = {So far, a number of approaches to synthesize microgel networks have been followed, while only in few cases a detailed control of the network architecture has been possible. Here, the photoinduced [2 + 2] cycloaddition reaction of cinnamylidene acetic acid (CAA) moieties coupled to four-arm star shaped oligo(ethylene glycol) (OEG) precursors was explored for the creation of microgels with defined polymer network structures. Based on a rational solvent selection and precursor dispersion in glass-capillary microfluidics, microgels could be successfully prepared by the proposed synthesis approach. Model reactions confirmed a quantitative network formation. Therefore, compared to common radical polymerization for microgel crosslinking, CAA-dimerization may be an alternative approach particularly when well defined network structures are desired.}, note = {Online available at: \url{https://doi.org/10.1016/j.reactfunctpolym.2016.12.015} (DOI). Ceylan Tuncaboylu, D.; Wischke, C.; Stoermann, F.; Lendlein, A.: Microgels from microfluidic templating and photoinduced crosslinking of cinnamylidene acetic acid modified precursors. Reactive and Functional Polymers. 2017. vol. 112, 68-73. DOI: 10.1016/j.reactfunctpolym.2016.12.015}}