@misc{behl_glucoseresponsive_shapememory_2020, 
author={Behl, M., Zhao, Q., Lendlein, A.},
title={Glucose-responsive shape-memory cryogels},
year={2020},
howpublished = {journal article},
doi = {https://doi.org/10.1557/jmr.2020.204},
abstract = {Boronic ester bonds can be reversibly formed between phenylboronic acid (PBA) and triol moieties. Here, we aim at a glucose-induced shape-memory effect by implementing such bonds as temporary netpoints, which are cleavable by glucose and by minimizing the volume change upon stimulation by a porous cryogel structure. The polymer system consisted of a semi-interpenetrating network (semi-IPN) architecture, in which the triol moieties were part of the permanent network and the PBA moieties were located in the linear polymer diffused into the semi-IPN. In an alkaline medium (pH = 10), the swelling ratio was approximately 35, independent of Cglu varied between 0 and 300 mg/dL. In bending experiments, shape fixity Rf ≈ 80% and shape recovery Rr ≈ 100% from five programming/recovery cycles could be determined. Rr was a function of Cglu in the range from 0 to 300 mg/dL, which accords with the fluctuation range of Cglu in human blood. In this way, the shape-memory hydrogels could play a role in future diabetes treatment options.},
note = {Online available at: \url{https://doi.org/10.1557/jmr.2020.204} (DOI). Behl, M.; Zhao, Q.; Lendlein, A.: Glucose-responsive shape-memory cryogels. Journal of Materials Research. 2020. vol. 35, no. 18, 2396-2404. DOI: 10.1557/jmr.2020.204}}